Zirconium (iv) chloride

Zirconium (iv) chloride, obeye aziwe njengozirconium tetrachloride, inefomula yefolemule ye-zrcl4 kanye nesisindo samangqamuzana esingu-233.04. Isetshenziswa kakhulu njenge-reagents yokuhlaziya, i-organic synthesis catalysts, ama-ejenti angavimba amanzi, ama-ejenti wokushuka

Igama lomkhiqizo:Zirconium chloride; Zirconium tetrachloride; Zirconium (iv) chloride

Isisindo Molecular: 233.04

Ama-EINEC: 233-058-2

Iphuzu elibilayo: 331 (Sublimation)

Ubuningi: 2.8

Ifomula yamakhemikhali:Zrcl44

Case:I-10026-11-6

Iphoyinti Lokuncibilika: 437

I-solubity yamanzi: incibilika emanzini abandayo

1.ProPerties

Izakhiwo Zomzimba Nezamakhemikhali

1. Umlingiswa: I-White Spysery Crystal noma i-Powder, ukudilizwa kalula.

2. Iphoyinti Lokuncibilika (℃): 437 (2533.3kpa)

3. Iphuzu elibilayo (℃): 331 (Sublimation)

I-4. Ubuningi obuhlobene (Amanzi = 1): 2.80

I-5. Ingcindezi ye-vapor egcwele (KPA): 0.13 (190 ℃)

I-6. Ingcindezi Ebucayi (MPA): 5.77

7. I-Solubity: incibilika emanzini abandayo, i-ethanol, ne-ether, infoluble e-benzenne, i-carbon tetrachloride, kanye ne-carbon dilumbuffide.

Kulula ukumunca umswakama kanye nomswakama, u-hydrolyzed ku-hydrogen chloride ne-zirconium oxychloride ngesisombululo somoya esinomswakama noma esikhangini esinamanzi, i-equation imi ngalendlela elandelayo:

Qinisa

1. Ukuqina: uzinzile

2. Izinto ezivinjelwe: Amanzi, ama-ANMine, ama-Alcohols, ama-acid, ama-esters, ama-ketones

3. Izimo zokugwema ukuxhumana: umoya onomswakama

4

5. Umkhiqizo wokubola: chloride

2.Ikuhlela

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Indlela ye-3.Synthetic

I-ICIANCIA KIRCONIA ne-carbon emnyama emnyama ngokuya ngesilinganiso se-molar of ukukalwa, hlanganisa ngokulinganayo bese uwabeka esikebheni se-porcelain. Beka isikebhe se-porcelain kushubhu porcelain bese usishisa ku-500 ℃ ekusakazweni kwegesi ye-chlorine ukuze kube ne-carvation. Qoqa umkhiqizo usebenzisa isicupho ekushiseni kwegumbi. Uma kucatshangelwa ukungenisa kwe-zirconium tetrachloride ngo-331 ℃, ishubhu ende engu-600mm ingasetshenziswa ukuphinda iye ekusakazweni kwegesi nge-hydrogen ngo-300-350 ℃ ukususa ama-oxides kanye ne-Ferric chloride eZirlonium Chloride.

4. Umthelela emvelweni

Izingozi Zezempilo

Umzila wokuhlasela: Ukuphefumula, ukumunca, ukuxhumana kwesikhumba.

Ingozi yezempilo: Ukuphefumula kungadala ukucasuka okuphefumula, ungagwinyi. Inokucasuka okunamandla futhi ingadala ukushiswa kwesikhumba kanye nomonakalo wamehlo. Ukuphathwa ngomlomo kungadala umuzwa ovuthayo emlonyeni nasemphinjeni, isicanucanu, ukugabha, ukugabha okunamanzi, izitulo zamagazi, ukuwa, ukuwa.

Imiphumela engamahlalakhona: ibangela i-glanuloma yesikhumba. Ukucasuka okuncane kwipheshana lokuphefumula.

 I-toxicology kanye nemvelo

Ubuthi obubi: I-LD501688mg / KG (Ukuphathwa ngomlomo kuya kumagundane); I-665mg / kg (igundane ngomlomo)

Izici ezinobungozi: Uma zingaphansi kokushisa noma emanzini, kubuthana futhi kukhiphe ukushisa, kukhulula intuthu enobuthi nezobuthi.

Umkhiqizo wokuhlanganisa (ukubola): i-hydrogen chloride.

Indlela Yokuhlola Labasethrotory: I-Plasma Spectroscopy (Indlela ye-Ninoosh 7300)

Ukuzimisela emoyeni: Qoqa isampula ngesihlungi, usinciphise nge-acid, bese ukukala nge-athomumuncu yokumuncwa kwe-athomu.

Amazinga Ezemvelo: Ukuphepha Kwezokuphepha Emsebenzini kanye Nezempilo (1974), isikhathi somoya esinesisindo esingu-5.

Ukuphendula okuphuthumayo okuvuzayo

Hlukanisa indawo evuthiwe yokuvuza, setha izimpawu eziyisixwayiso ezizungezile, bese uphakamisa abasebenzi abaphuthumayo ukuthi bagqoke imaski yegesi kanye nezingubo zokuvikela amakhemikhali. Ungangeni ekuxhumaneni okuqondile ngento evuthiwe, gwema uthuli, ukhubeke ngokucophelela, ulungiselele isixazululo samanzi acishe abe ngu-5% noma i-acid, kancane kancane engeza i-dilutes amona amanzi kuze kube yilapho kulahla. Ungahlanza futhi ngenani elikhulu lamanzi, bese uphonsa amanzi okugeza ohlelweni lwamanzi lwase-wastewater. Uma kunenani elikhulu lokuvuza, lisuse ngaphansi kokuholwa ngabasebenzi bezobuchwepheshe. Indlela yokulahla imfucuza: Hlanganisa imfucuza nge-sodium bicarbonate, fafaza ngamanzi e-ammonia, bese wengeza iqhwa elichotshoziwe. Ngemuva kokusabela kuyeka, hlambulula ngamanzi ungene endle.

 Izindlela Zokuvikela

Ukuvikelwa kokuphefumula: Uma kuvezwa uthuli, kufanele kugqokwe igesi. Gqoka izinto zokuphefumula ezinazo lapho kunesidingo.

Ukuvikelwa kwamehlo: Gqoka ama-Goggles amakhemikhali ukuphepha.

Izingubo Zokuvikela: Gqoka izingubo zomsebenzi (ezenziwe ngezinto zokulwa nokukhulisa).

Ukuvikelwa Kwezandla: Gqoka amagilavu ​​enjoloba.

Okunye: Ngemuva komsebenzi, geza futhi ushintshe izingubo. Gcina izingubo ezingcoliswe ubuthi ngokwahlukana bese uzisebenzisa ngemuva kokugeza. Gcina imikhuba emihle yokuhlanzeka.

 Izindlela Zomsizi Wokuqala

Ukuxhumana kwesikhumba: Ngokushesha hlambulula ngamanzi okungenani imizuzu eyi-15. Uma kukhona ukushiswa, funa ukwelashwa.

Ukuthintwa ngamehlo: Ngokushesha ukuphakamisa izinkophe bese hlambulula ngamanzi agelezayo noma usawoti womzimba okungenani imizuzu eyi-15.

Ukuphefumula: Susa ngokushesha endaweni yesehlakalo uye endaweni ngomoya omusha. Gcina ipheshana lokuphefumula elingaguquki. Yenza ukuphefumula kokufakelwa uma kunesidingo. Funa ukunakekelwa kwezokwelashwa.

Ukungeniswa: Lapho isiguli siphapheme, hlamba umlomo waso ngokushesha, unganaki ukuhlanza, uphuze ubisi noma iqanda elimhlophe. Funa ukunakekelwa kwezokwelashwa.

Indlela yokucisha umlilo: Foam, isikhutha, isihlabathi, i-powder eyomile.

Indlela engu-5.Storage

Gcina endaweni yokugcina epholile, eyomile, futhi enomoya omuhle. Gwema kude nasezinhlangothini nasemithonjeni yokushisa. Ukupakishwa kumele kuvalwe uphawu futhi kuvikelwe kumswakama. Kufanele igcinwe ngokwahlukana kusuka kuma-acid, ama-Amines, ama-alcohols, ama-esters, njll., Futhi uvikele ukuxuba ukugcina. Indawo yokugcina kufanele ifakwe ngezinto ezifanele ukuqukatha ukuvuza.

6 Ukuhlelwa kwedatha ye-computational chemistry

1

2. Inani labanikeli be-hydrogen Bond: 0

3. Inani lama-hydrogen bond receptors: 0

4. Inani le-rotatable Chemical Bond: 0

5. Inani lamaTautomers: Akukho

I-6. I-topological molecule polarity survace Area: 0

7. Inani lama-athomu asindayo: 5

8. Ukukhokhiswa okungaphezulu: 0

9. Ubunzima: 19.1

10. Inani lama-athomu we-isotope: 0

11. Thola inani lezikhungo zokwakheka kwe-athomu: 0

12. Inani lezikhungo zokwakha ze-athomu ezingaqinisekile: 0

13. Thola inani lezikhungo ze-Chemical Bond Stereo: 0

14. Inani lemibhalo eqinisekisiwe yamakhemikhali: 0

15. Inani lamayunithi webhondi e-combared: 1